| Title |
The Kinetic and Thermodynamic Behavior of Oxygen in Ni and Pd |
| Abstract |
Solid-state electrochemical measurements were made to determine diffusivities and thermodynamic functions of oxygen in Ni and Pd. Diffusion of oxygen was caused by applying preselected potentials between the reference and specimen electrodes and was monitored by measuring time-dependent potentials and or currents. The following results were obtained for the diffusivities and terminal solubilities of oxygen in solid Ni and Pd : (수식) The thermodynamic properties of the Ni-O and Pd-O solutions follow the general tendency of periodic behavior from group to group. |