| Title |
Electronic, Magnetic & Optical Materials : Magnetic Properties and Corrosion Resistance of (FeNiCr) Amorphous Alloys for Filtering Media Use |
| Authors |
임종만(J. W. Lim); 남궁정(J. Nam Kung); 김문철(M. C. Kim); 노태환(T. H. Noh) |
| ISSN |
1738-8228(ISSN), 2288-8241(eISSN) |
| Keywords |
Amorphous alloys; Filtering media; Magnetic properties; Corrosion resistance |
| Abstract |
With the object of developing a ferromagnetic filtering media used in electromagnetic filtering process of iron & steel industries, addition effects of Cr and Ni on magnetic properties and corrosion resistance for Fe_80P_20 amorphous ribbon alloy have been investigated. In (FeCr)_80P_20 ternary alloys, the soft magnetic properties and corrosion resistance were largely enhanced upon Cr addition of about 5 at%, although considerable decrease in saturation magnetization occurred. However the corrosion rate was thought to be still high for practical use. If the Fe was substituted by some Ni to form a quarternary Fe-Ni-Cr-P alloys, decrease of the saturation magnetization was strongly suppressed. Moreover the soft magnetic properties and corrosion resistance were improved to a great extent as compared to Fe_75Cr_5P_20 amorphous alloy. For Fe_75Ni_5Cr_5P_20 amorphous alloy, the values of B_10, M_s and H_c were 6.9 kG, 110 emu/g and 0.24 Oe, respectively. The corrosion rate was measured to be very low(less than 0.2 ㎜/ yr) in 5 wt% HCl solution(room temperature) and 2 wt% NaOH solution(60℃). The good soft magnetic properties and corrosion resistance of Fe_75Ni_5Cr_5P_20 amorphous alloy were attributed to the decrease in saturation magnetostriction and more active formation of CrO_X(OH)_(3-2x)·nH_2O passive films by the combined addition of Ni and Cr. |