| Title |
Solvent Extraction of Sn(4) from Hydrochloric Acid Solution by Alamine 336 |
| Authors |
안재우(Jae Woo Ahn); 서재성(Jae Seong Seo); 이만승(Man Seung Lee) |
| DOI |
https://doi.org/10.3365/KJMM.2010.48.10.929 |
| ISSN |
1738-8228(ISSN), 2288-8241(eISSN) |
| Keywords |
Solvent extraction; Alamine336; tin; HCl; stripping |
| Abstract |
The solvent extraction behavior of Sn(IV) from hydrochloric acid was investigated using Alamine336 (Tri-n-cotylamine) as an extractant. The experimental parameters of the concentration of the HCl solution, chloride ions, extractant, and Sn(IV) were assessed. The results showed that the extraction percentage of Sn(IV) was more than 95% in our experimental range and was only slightly affected by the HCl concentration. The extraction reaction of Sn(IV) by Alamine 336 from the chloride solution was identified as follows: SnCl6(2-)+2R(3)NHCl(org)=(R3NH)2SnCl6(org)+2Cl-, and K=6.3×10(4). Stripping experiments of Sn(IV) from the loaded organic phase were done by using several stripping agents. A stripping percentage of 90% was obtained with a 2.0 M NaOH solution. |