The Journal of
the Korean Journal of Metals and Materials

The Journal of
the Korean Journal of Metals and Materials

Monthly
  • pISSN : 1738-8228
  • eISSN : 2288-8241

Editorial Office

Title Fabrication and Electrical Characterization of p/n PbSe Diodes
Authors 황보석호(Sukho Hwangbo); 이제원(Jewon Lee)
DOI https://doi.org/10.3365/KJMM.2024.62.2.94
Page pp.94-105
ISSN 1738-8228(ISSN), 2288-8241(eISSN)
Keywords PbSe; Co-sputtering; Nickel doping; p-n PbSe Diode; Hall measurement; I-V Curve; Photo Current
Abstract Lead selenide (PbSe) diodes were fabricated using a magnetron sputtering process system with a pulsed DC power supply and a 2-inch PbSe target with a purity of 5N. For p-type PbSe thin films, the process variable was the oxygen ratio in the mixed gas of argon and oxygen. The electrical characteristics of the thin films were observed after heat treatment. For the n-type PbSe, nickel (Ni) was used as a doping material. The deposition and doping were performed simultaneously using a co-sputtering method. During co-sputtering, the input power of the Ni sputter gun was adjusted as a process variable. Hall measurement experiments were performed to measure the doping concentration and resistivity of both the p-type and n-type PbSe semiconducting films. The maximum doping concentration was 2.33×1019 cm-3 for p-type PbSe and 7.55×1020 cm-3 for n-type PbSe thin films, respectively. The p-n junction IV curve showed that the lowest forward voltage generation point, Vf, was 1.5 V and the reverse breakdown voltage was -4.3 V. In the photocurrent measurement, the photo sensitivities of the heat-treated samples were higher than that of the non-treated sample, and the maximum value was 5.148. Photo responsivity was also higher in the heat-treated samples. Its maximum was 0.7306 mA / W.(Received 9 June, 2023; Accepted 8 November, 2023)