The Journal of
the Korean Journal of Metals and Materials

The Journal of
the Korean Journal of Metals and Materials

Monthly
  • pISSN : 1738-8228
  • eISSN : 2288-8241

Editorial Office


  1. ๋ถ€๊ฒฝ๋Œ€ํ•™๊ต ์‹ ์†Œ์žฌ์‹œ์Šคํ…œ๊ณตํ•™๊ณผ (Department of Materials System Engineering, Pukyong National University, Busan 48513, Republic of Korea)
  2. ๊ฒฝ๋‚จ๋Œ€ํ•™๊ต ์‹ ์†Œ์žฌ๊ณตํ•™๊ณผ (Department of Advanced Materials Science and Engineering, Kyungnam University, Changwon 51767, Republic of Korea)
  3. ๋‘์‚ฐ์ค‘๊ณต์—… GT์†Œ์žฌ๊ธฐ์ˆ ํŒ€ (Gas Turbine Materials Engineering Team, Doosan Heavy Industries and Construction, Changwon 51711, Republic of Korea)
  4. ํ•œ๊ตญ์žฌ๋ฃŒ์—ฐ๊ตฌ์› ๊ณ ์˜จ์žฌ๋ฃŒ์—ฐ๊ตฌ์‹ค (High Temperature Materials Group, Korea Institute of Materials Science, Changwon 51508, Republic of Korea)



CM247LC superalloy, repair welding, heat-affected zone, liquation cracking susceptibility, modifiedvarestraint test

1. ์„œ ๋ก 

CM247LC๋Š” Mar-M247ํ•ฉ๊ธˆ์˜ ์ผ๋ถ€ ์„ฑ๋ถ„์„ ์กฐ์ ˆํ•˜์—ฌ ์ฃผ์กฐ ๊ฑด์ „์„ฑ ๋ฐ ๊ธฐ๊ณ„์  ์„ฑ์งˆ์„ ๊ฐœ์„ ์‹œํ‚จ Ni๊ณ„ ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ์ด๋ฉฐ, ์•ฝ 60%์˜ ฮณโ€™ ์„์ถœ์ƒ์ด ์šฐ์ˆ˜ํ•œ ๊ณ ์˜จ ๋ฌผ์„ฑ์„ ๋ฐœํ˜„ํ•œ๋‹ค[1-3]. ์ตœ๊ทผ ๊ตญ๋‚ด์—์„œ๋Š” CM247LC ํ•ฉ๊ธˆ์˜ ๊ฐ€์Šคํ„ฐ๋นˆ ๋ธ”๋ ˆ์ด๋“œ ์ ์šฉ์„ ์œ„ํ•œ ์†Œ์žฌ ๋ฐ ๊ฐ€๊ณต๊ธฐ์ˆ  ๊ตญ์‚ฐํ™” ์—ฐ๊ตฌ๊ฐ€ ์ง„ํ–‰์ค‘์ด๋‹ค. ๋ธ”๋ ˆ์ด๋“œ๋Š” ์ œ์กฐ ์ตœ์ข… ๋‹จ๊ณ„ ๋ฐ ์žฌ์ƒ๊ณผ์ •์—์„œ ์šฉ์ ‘ ๋ฐ ์ ‘ํ•ฉ๊ณต์ •์„ ํ•„์ˆ˜์ ์œผ๋กœ ์ˆ˜๋ฐ˜ํ•˜๋ฉฐ, ์šฉ์ ‘๋ถ€ ๊ฑด์ „์„ฑ์€ ๋ธ”๋ ˆ์ด๋“œ์˜ ๊ธฐ๊ณ„์ , ํ™”ํ•™์  ์„ฑ๋Šฅ๊ณผ ์ง๊ฒฐ๋œ๋‹ค๊ณ  ํ•  ์ˆ˜ ์žˆ๋‹ค. ํ•˜์ง€๋งŒ ๋‚œ์šฉ์ ‘(non-weldable) ์†Œ์žฌ๋กœ ์ž˜ ์•Œ๋ ค์ง„ CM247LC ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ์€ ์šฉ์ ‘[4-6] ๋ฐ ์ ์ธต์ œ์กฐ[7-9] ์‹œ ๋‹ค์–‘ํ•œ ๊ณ ์˜จ๊ท ์—ด(์‘๊ณ , ์•กํ™”, ์—ฐ์„ฑ์ €ํ•˜ ๋ฐ ๋ณ€ํ˜•์‹œํšจ๊ท ์—ด) ํ˜„์ƒ์ด ๋ณด๊ณ ๋˜๊ณ  ์žˆ๋Š” ๋ฐ”, ๊ฐ ๊ท ์—ด ํ˜„์ƒ์˜ ๋ฉด๋ฐ€ํ•œ ์ œ์–ด ์—†์ด๋Š” ๊ฑด์ „ํ•œ ์šฉ์ ‘๋ถ€ ์ œ์กฐ๊ฐ€ ๋ถˆ๊ฐ€๋Šฅํ•˜๋‹ค. ์ด๋Ÿฌํ•œ ๊ด€์ ์—์„œ ๋ณธ ์ €์ž๋Š” CM247LC ํ•ฉ๊ธˆ ํ„ฐ๋นˆ ๋ธ”๋ ˆ์ด๋“œ ์ ์šฉ์„ ์œ„ํ•œ ์šฉ์ ‘๋ถ€ ์‘๊ณ  ๊ท ์—ด[10] ๋ฐ ์•กํ™”๊ท ์—ด[4,11,12] ๋ฏผ๊ฐ๋„ ์ €๊ฐ๊ธฐ์ˆ  ์—ฐ๊ตฌ๊ฒฐ๊ณผ๋ฅผ ๋ณด๊ณ ํ•œ ๋ฐ” ์žˆ์œผ๋ฉฐ, ํ•ด๋‹น ์—ฐ๊ตฌ๋“ค์€ ์ฃผ๋กœ ๋ธ”๋ ˆ์ด๋“œ ์ œ์กฐ ์‹œ์˜ ๋‹จ์ธต(single pass)์šฉ์ ‘ ๊ณต์ •์— ์ดˆ์ ์„ ๋งž์ถ”๊ณ  ์žˆ๋‹ค.

ํ•œํŽธ, ๊ณ ์˜จ ๊ณ ์••์˜ ๊ฐ€์Šคํ„ฐ๋นˆ ๊ฐ€๋™ ํ™˜๊ฒฝ์— ์žฅ์‹œ๊ฐ„ ๋…ธ์ถœ๋  ๊ฒฝ์šฐ, ๋ธ”๋ ˆ์ด๋“œ์—๋Š” ์—ด์ถฉ๊ฒฉ ๋ฐ ํ”ผ๋กœ ๋“ฑ์— ์˜ํ•œ ์†์ƒ๋ถ€๊ฐ€ ๋ฐœ์ƒํ•˜๋ฉฐ, ์†์ƒ ์ •๋„์— ๋”ฐ๋ผ ์‹ ํ’ˆ ๊ต์ฒด ๋˜๋Š” ๋ณด์ˆ˜์šฉ์ ‘(repair welding)์„ ํ†ตํ•œ ์žฌ์ƒ ๋ธ”๋ ˆ์ด๋“œ ์ ์šฉ ๋“ฑ์ด ๊ฒ€ํ† ๋ ์ˆ˜ ์žˆ๋‹ค. ํŠนํžˆ CM247LC ํ•ฉ๊ธˆ ์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด์€, ์—ด์˜ํ–ฅ๋ถ€์— ์กด์žฌํ•˜๋Š” ฮณ/ฮณโ€™ ๊ณต์ •์กฐ์ง์˜ ๋ถ€๋ถ„์  ์•ก์ƒํ™” ๋ฐ MCํ˜• ํƒ„ํ™”๋ฌผ์˜ ์กฐ์„ฑ์  ์•ก์ƒํ™”์— ์˜ํ•ด ํ˜•์„ฑ๋˜๋Š” ๊ฒƒ์œผ๋กœ ํŒ๋ช…๋˜์—ˆ์œผ๋ฉฐ[4], ๋ธ”๋ ˆ์ด๋“œ ๋‹จ์ธต์šฉ์ ‘ ์‹œ์—๋Š” ์šฉ์ ‘ ์ „์—ด์ฒ˜๋ฆฌ์— ์˜ํ•œ ฮณ/ฮณโ€™ ๊ณต์ •์กฐ์ง ๊ท ์งˆํ™” ๋ฐ MCํ˜• ํƒ„ํ™”๋ฌผ ์ €๊ฐ์„ ํ†ตํ•ด ์•กํ™” ๊ท ์—ด ๋ฐœ์ƒ์ด ์–ต์ œ ๊ฐ€๋Šฅํ•œ ๊ฒƒ์œผ๋กœ ๋ณด๊ณ ๋˜๊ณ  ์žˆ๋‹ค[12]. ํ•˜์ง€๋งŒ ๊ทธ๋ฆผ 1์— ์„ค๋ช…ํ•œ ๋‹ค์ธต(multi-pass) ๋ณด์ˆ˜์šฉ์ ‘ ์‹œ์—๋Š”, ์žฅ์‹œ๊ฐ„ ์—ด๊ฐ„๋…ธ์ถœ์— ์˜ํ•œ CM247LC ํ•ฉ๊ธˆ ๋ฏธ์„ธ์กฐ์ง ๋ณ€ํ™” (๊ณผ์‹œํšจ ๋“ฑ), ๋‹ค์ธต ์šฉ์ ‘๊ณผ์ •์˜ ์žฌ์šฉ์œต ๋ฐ ๋ณต์žกํ•œ ์šฉ์ ‘ ์—ด์ด๋ ฅ์— ์˜ํ•ด, ์ƒ๊ธฐ์˜ ๋‹จ์ธต์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด ๋ฏผ๊ฐ๋„ ํ‰๊ฐ€๊ฒฐ๊ณผ์— ๊ธฐ๋ฐ˜ํ•œ ์šฉ์ ‘๊ณต์ • ์„ค๊ณ„์— ํ•œ๊ณ„์ ์ด ์กด์žฌํ•  ์ˆ˜ ๋ฐ–์— ์—†๋‹ค. ๋”ฐ๋ผ์„œ CM247LC ํ•ฉ๊ธˆ์˜ ๋ฌด๊ท ์—ด ๋ณด์ˆ˜ ์šฉ์ ‘๋ถ€ ์ œ์กฐ๋ฅผ ์œ„ํ•ด์„œ๋Š” ๋‹ค์ธต ์šฉ์ ‘ ์—ด์˜ํ–ฅ๋ถ€๋ฅผ ์žฌํ˜„ํ•œ ๋ชจ์‚ฌ์‹คํ—˜ ๋“ฑ ์•กํ™”๊ท ์—ด ๊ฑฐ๋™์— ๋Œ€ํ•œ ํ†ตํ•ด ๋ฉด๋ฐ€ํ•œ ์‚ฌ์ „ ๊ฒ€ํ† ๊ฐ€ ํ•„์š”ํ•˜๋‚˜, ์ด์— ์ฒด๊ณ„์ ์ธ ๊ตญ๋‚ด ์—ฐ๊ตฌ๋Š” ์ „๋ฌดํ•œ ์‹ค์ •์ด๋‹ค.

๋ณธ ์—ฐ๊ตฌ์—์„œ๋Š” CM247LC ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ ํ„ฐ๋นˆ ๋ธ”๋ ˆ์ด๋“œ ๋ณด์ˆ˜์šฉ์ ‘ ์‹œ, ๋ธ”๋ ˆ์ด๋“œ์˜ ์žฌ์šฉ์œต์ด ๋ฐœ์ƒํ•˜๋Š” ์ดˆ์ธต(1st layer) ์ดํ›„, ๊ทธ ์ค‘์—์„œ๋„ ์ œ2์ธต(2nd layer) ์—ด์˜ํ–ฅ๋ถ€ ์•กํ™”๊ท ์—ด ๊ฑฐ๋™์— ์ดˆ์ ์„ ๋งž์ถ”์–ด ๊ทธ ๋ฏผ๊ฐ๋„๋ฅผ ์ •๋Ÿ‰ ํ‰๊ฐ€ํ•˜์˜€๋‹ค (๊ทธ๋ฆผ 1). ์ด๋ฅผ ์œ„ํ•ด pre-weld Varestraint ์ด๋ผ๋Š” ์ˆ˜์ •๋œ ๋ฐฉ์‹์˜ ์‹œํ—˜ ๊ณผ์ •์„ ๊ณ ์•ˆํ•˜์˜€์œผ๋ฉฐ, ํ‰๊ฐ€ ๊ฒฐ๊ณผ๋Š” ์„ ํ–‰์—ฐ๊ตฌ์—์„œ ๋ณด๊ณ ํ•œ ๋‹จ์ธต ์šฉ์ ‘๋ถ€์˜ ์•กํ™”๊ท ์—ด ๋ฏผ๊ฐ๋„์™€ ๋น„๊ต ๊ฒ€ํ† ํ•˜์˜€๋‹ค. ๋น„๊ต ๊ฒฐ๊ณผ๋Š” ๋ฏธ์„ธ์กฐ์ง ๋ณ€ํ™”๋ถ„์„ ๋ฐ ์—ด์—ญํ•™์  ๊ณ„์‚ฐ์„ ํ†ตํ•ด ๊ณ ์ฐฐํ•จ์œผ๋กœ์จ, ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด ์ œ์–ด๋ฅผ ์œ„ํ•œ ์•ผ๊ธˆํ•™์  ํ•ต์‹ฌ์ธ์ž๋ฅผ ์ œ์‹œํ•˜๊ณ ์ž ํ•œ๋‹ค. ์ตœ์ข…์ ์œผ๋กœ ๋„์ถœ๋œ ๊ฒฐ๊ณผ๋“ค์€ CM247LC ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ ๊ฐ€์Šคํ„ฐ๋นˆ ๋ธ”๋ ˆ์ด๋“œ์˜ ๋ณด์ˆ˜์šฉ์ ‘ ๊ณต์ • ์กฐ๊ฑด ์ตœ์ ํ™” ๋ฐ ์ œ์กฐ์— ํ™œ์šฉํ•˜๊ณ ์ž ํ•œ๋‹ค.

2. ์‚ฌ์šฉ์žฌ๋ฃŒ ๋ฐ ์‹คํ—˜๋ฐฉ๋ฒ•

2.1 ์‚ฌ์šฉ์žฌ๋ฃŒ

ํ‘œ 1์€ CM247LC ํ•ฉ๊ธˆ ํ™”ํ•™์„ฑ๋ถ„์„ ๋‚˜ํƒ€๋‚ธ๋‹ค. Cannon Muskegon ์‚ฌ์˜ ์ƒ์šฉ ๋ชจํ•ฉ๊ธˆ์„ ์ด์šฉํ•ด ํŒ์žฌ ํ˜•์ƒ์œผ๋กœ ์ฃผ์กฐํ•˜์˜€์œผ๋ฉฐ, ์ฃผ์กฐ์žฌ๋Š” ์šฉ์ฒดํ™” ์—ด์ฒ˜๋ฆฌ(1505 K โ€“ 120๋ถ„) ๋ฐ ์‹œํšจ ์—ด์ฒ˜๋ฆฌ(1145 K โ€“ 1200 ๋ถ„)๋ฅผ ์‹ค์‹œํ•˜์—ฌ Varestraint ์‹œํ—˜ํŽธ์„ ์ œ์ž‘ํ•˜์˜€๋‹ค.

2.2 Varestraint ์‹œํ—˜ ๋ฐ ๊ฐ€์Šคํ……์Šคํ… ์•„ํฌ์šฉ์ ‘

CM247LC ํ•ฉ๊ธˆ ๋ณด์ˆ˜ ์šฉ์ ‘๋ถ€(์ œ2์ธต ์—ด์˜ํ–ฅ๋ถ€) ์•กํ™”๊ท ์—ด ๋ฏผ๊ฐ๋„๋ฅผ ํ‰๊ฐ€ํ•˜๊ธฐ ์œ„ํ•ด pre-weld Varestraint ์‹œํ—˜์„ ์‹ค์‹œํ•˜์˜€๋‹ค. ๊ทธ๋ฆผ 2๋Š” ๋ณธ ์—ฐ๊ตฌ์—์„œ ์‚ฌ์šฉํ•œ (a)Varestraint ์‹œํ—˜ ์žฅ์น˜ ์™ธ๊ด€ ๋ฐ (b)์‹œํ—˜ํŽธ ๋ฐฐ์น˜์— ๋Œ€ํ•œ ๋ชจ์‹๋„๋ฅผ ๋‚˜ํƒ€๋‚ธ๋‹ค. ๊ทธ๋ฆผ 3์€ ๋ณธ ์—ฐ๊ตฌ์—์„œ ๊ณ ์•ˆํ•œ pre-weld Varestraint ์‹œํ—˜๊ณผ์ •์„ ์„ค๋ช…ํ•˜๊ณ  ์žˆ๋‹ค. ์‹œํšจ ์—ด์ฒ˜๋ฆฌ๋œ CM247LC ํ•ฉ๊ธˆ ์‹œํ—˜ํŽธ(150 ร— 50 ร— 3 mm)์— ๊ฐ€์Šคํ……์Šคํ… ์•„ํฌ์šฉ์ ‘(gas tungsten arc welding, GTAW)์„ ์ด์šฉํ•ด ์ œ์‚ด์šฉ์ ‘(์ดํ•˜ pre-welding) ํ•˜์˜€๊ณ , ํ•ด๋‹น ๋น„๋“œ ์ค‘์•™๋ถ€์— ์•„ํฌ ์  ์šฉ์ ‘(arc spot welding)์„ ์ด์šฉํ•œ Varestraint ์‹œํ—˜์„ ์‹ค์‹œํ•˜์˜€๋‹ค. ์‹œํ—˜๊ณผ์ • ์ƒ์˜ pre-welding์€ ๋ณด์ˆ˜์šฉ์ ‘ ์ดˆ์ธต, ์•„ํฌ ์  ์šฉ์ ‘์€ ์ œ2์ธต๋ถ€์— ํ•ด๋‹นํ•œ๋‹ค. Varestraint ์‹œํ—˜ ์‹œ์—๋Š” ๊ทธ๋ฆผ 2(b)์™€ ๊ฐ™์ด ์•„ํฌ์  ์šฉ์ ‘ ์ข…๋ฃŒ์™€ ๋™์‹œ์— 400 mm/s ์†๋„๋กœ ๊ตฝํž˜ ๋ณ€ํ˜•์„ ๋ถ€๊ฐ€ํ•˜์˜€๊ณ , ์—ด์˜ํ–ฅ๋ถ€์— ์ƒ์„ฑ๋œ ๊ท ์—ด ๊ธธ์ด๋กœ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด ๋ฏผ๊ฐ๋„๋ฅผ ํ‰๊ฐ€ํ•˜์˜€๋‹ค. Pre-welding ์กฐ๊ฑด ๋ฐ ๋ถ€๊ฐ€ ๋ณ€ํ˜•๋ฅ  ๋“ฑ์˜ Varestraint ์‹œํ—˜ ์ฃผ์š” ์กฐ๊ฑด์€ ํ‘œ 2์— ์š”์•ฝํ•˜์˜€๋‹ค. ์ƒ์„ฑ๋œ ๊ท ์—ด๊ธธ์ด๋Š” ์‹ค์ฒดํ˜„๋ฏธ๊ฒฝ(ISM-PM200SB, Insize)์œผ๋กœ ์ธก์ •ํ•˜์˜€๋‹ค. ์•กํ™”๊ท ์—ด ๊ธธ์ด๋ฅผ ์˜จ๋„๋ฒ”์œ„๋กœ ๋ณ€ํ™˜ํ•˜๊ธฐ ์œ„ํ•ด Varestraint ์‹œํ—˜ ๊ท ์—ด ๋ฐœ์ƒ์‹œ์ ์˜ ์˜จ๋„๋ถ„ํฌ๋ฅผ ์—ดํ™”์ƒ์นด๋ฉ”๋ผ(A655sc, FLIR)๋กœ ๊ฐ€์‹œํ™”ํ•˜์˜€์œผ๋ฉฐ(๊ทธ๋ฆผ 2(a)), ํ•ด๋‹น ๊ฒฐ๊ณผ๋ฅผ ์ด์šฉํ•ด ๋ณด์ˆ˜์šฉ์ ‘๋ถ€์˜ ์•กํ™”๊ท ์—ด ๋ฐœ์ƒ์˜จ๋„๋ฒ”์œ„ (liquation cracking temperature range, LCTR)๋ฅผ ๋„์ถœํ•˜์˜€๋‹ค. ๋ณธ ์—ฐ๊ตฌ์—์„œ ์‚ฌ์šฉ๋œ ๊ณ ์† ์—ดํ™”์ƒ์นด๋ฉ”๋ผ ์‚ฌ์–‘์€ ํ‘œ 3์— ์š”์•ฝํ•˜๊ณ  ์žˆ๋‹ค. CM247LC ์šฉ์ ‘๋ถ€์˜ ๋ฏธ์„ธ์กฐ์ง ๋ถ„์„์„ ์œ„ํ•ด GTAW๋ฅผ ์‹ค์‹œํ•˜์˜€์œผ๋ฉฐ ์šฉ์ ‘์กฐ๊ฑด์€ ํ‘œ 2์˜ prewelding ์กฐ๊ฑด๊ณผ ๋™์ผํ•˜๊ฒŒ ์ ์šฉํ•˜์˜€๋‹ค.

2.3 ๋ฏธ์„ธ์กฐ์ง ๋ถ„์„

์šฉ์ ‘๋ถ€ ๋ฐ Varestraint ์‹œํ—˜๋ถ€ ๋ฏธ์„ธ์กฐ์ง์€ ์ „์žํƒ์นจ๋ฏธ์„ธ ๋ถ„์„๊ธฐ(Electron Probe Micro Analyzer, EPMA, JXA-8530F, JEOL) ๋ฐ ํ›„๋ฐฉ์‚ฐ๋ž€์ „์žํšŒ์ ˆ(Electron Backscatter Diffraction, EBSD, Velocity Super, EDAX) ๊ธฐ๋ฒ•์„ ํ†ตํ•ด ๋ถ„์„ํ•˜์˜€๋‹ค.

3. ์‹คํ—˜๊ฒฐ๊ณผ ๋ฐ ๊ณ ์ฐฐ

3.1 CM247LC ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ ์šฉ์ ‘๋ถ€ ๋ฏธ์„ธ์กฐ์ง

๊ทธ๋ฆผ 4๋Š” EBSD๋ฅผ ํ†ตํ•ด ๋ถ„์„ํ•œ CM247LC ํ•ฉ๊ธˆ ์šฉ์ ‘๋ถ€(pre-welding)์˜ ๋Œ€ํ‘œ์ ์ธ ๋‹จ๋ฉด ๋ฏธ์„ธ์กฐ์ง์„ ๋‚˜ํƒ€๋‚ธ๋‹ค. โ€œImage quality(IQ) mapโ€์— ๋‚˜ํƒ€๋‚ด๋“ฏ์ด, ์…€ ํ˜•ํƒœ์˜ ์‘๊ณ  ๊ฒฐ์ •๋ฆฝ๊ณผ ํ•จ๊ป˜ ๊ฒฐ์ •๋ฆฝ๊ณ„์—๋Š” 2์ฐจ์ƒ๋“ค์ด ๊ด€์ฐฐ๋˜๋ฉฐ, โ€œPhase mapโ€์— ๋ณด์ด๋“ฏ์ด ํ•ด๋‹น 2์ฐจ์ƒ๋“ค์€ MCํ˜• ํƒ„ํ™”๋ฌผ์ธ ๊ฒƒ์œผ๋กœ ๋™์ •๋˜์—ˆ๋‹ค. ํŠนํžˆ ์ €๋ฐฐ์œจ ์ด๋ฏธ์ง€์ƒ์˜ โ€œAโ€ ์˜์—ญ์„ ํ™•๋Œ€๋ถ„์„ํ•œ ๊ฒฐ๊ณผ (โ€œEnlarged Aโ€), ๊ฒฐ์ •๋ฆฝ๊ณ„์—๋Š” MC ํƒ„ํ™”๋ฌผ๋ฟ๋งŒ ์•„๋‹ˆ๋ผ ฮณ/ฮณ' ๊ณต์ • ์กฐ์ง์ด ํ˜•์„ฑ๋˜์—ˆ์Œ์„ ๊ด€์ฐฐํ•  ์ˆ˜ ์žˆ์œผ๋ฉฐ, ๊ฒฐ์ •๋ฆฝ ๋‚ด์—๋Š” ฮณ' ์„์ถœ์ƒ๋„ ํ™•์ธ๋œ๋‹ค. CM247LC ํ•ฉ๊ธˆ ์‘๊ณ (์ฃผ์กฐ, ์ ์ธต ์ œ์กฐ ๋“ฑ) ๊ณผ์ •์ƒ์˜ ์ฃผ๋œ 2์ฐจ ์กฐ์ง๋“ค์€ MC ํ˜• ํƒ„ํ™”๋ฌผ ๋ฐ ฮณ/ฮณ' ๊ณต์ • ์กฐ์ง์ธ ๊ฒƒ์œผ๋กœ ์ž˜ ์•Œ๋ ค์ ธ ์žˆ์œผ๋ฉฐ[3,9,11], ์ด๋Ÿฌํ•œ ํŠน์ง•์€ ์šฉ์ ‘๊ธˆ์†์—์„œ๋„ ์ž˜ ํ™•์ธ๋œ๋‹ค. ๊ทธ๋ฆผ 5๋Š” ๊ทธ๋ฆผ 4 โ€œAโ€ ์˜์—ญ์— ๋Œ€ํ•œ EPMA ๋ถ„์„๊ฒฐ๊ณผ๋ฅผ ๋‚˜ํƒ€๋‚ธ๋‹ค. ์šฉ์ ‘ ์‘๊ณ  ์‹œ, MC ํƒ„ํ™”๋ฌผ(M=Ti,Ta,Hf ๋“ฑ) ๋ฐ ฮณ'์ƒํ˜•์„ฑ์›์†Œ (Al)์˜ ๋ฏธ์„ธํŽธ์„(microsegregation) ๊ฑฐ๋™์„ ๋ช…ํ™•ํžˆ ํ™•์ธํ•  ์ˆ˜ ์žˆ์œผ๋ฉฐ, ๋”ฐ๋ผ์„œ ๊ฒฐ์ •๋ฆฝ๊ณ„์— ์กด์žฌํ•˜๋Š” 2์ฐจ์ƒ ๋“ค์€ ํ•ด๋‹น ํ˜•์„ฑ์›์†Œ๋“ค์˜ ์‘๊ณ ํŽธ์„ ๊ฑฐ๋™๊ณผ ์—ฐ๊ณ„๋œ ๊ฒฐ๊ณผ๋กœ ์‚ฌ๋ฃŒ๋œ๋‹ค.

3.2 CM247LC ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด ๊ฑฐ๋™

๊ทธ๋ฆผ 6์€ pre-weld Varestraint ์‹œํ—˜(๋ถ€๊ฐ€ ๋ณ€ํ˜•๋ฅ : 3%) ๊ฒฐ๊ณผ๋ฅผ ๋‚˜ํƒ€๋‚ธ๋‹ค. ์•„ํฌ ์ ์šฉ์ ‘๋ถ€๋ฅผ ์ค‘์‹ฌ์œผ๋กœ ๊ณ ์˜จ๊ท ์—ด ํ˜•์„ฑ์„ ํ™•์ธํ•  ์ˆ˜ ์žˆ์œผ๋ฉฐ (โ€œAโ€ ๋ฐ โ€œBโ€ ์˜์—ญ), ํ˜•์„ฑ ์œ„์น˜์— ๋”ฐ๋ผ ์šฉ์œต์ง€ ๊ฒฝ๊ณ„์„ (fusion line) ๋‚ด์˜ ๊ท ์—ด๊ณผ ์—ด์˜ํ–ฅ๋ถ€ ๊ท ์—ด๋กœ ๊ตฌ๋ถ„ ๊ฐ€๋Šฅํ•˜๋‹ค. ๊ทธ๋ฆผ 7์€ ๊ทธ๋ฆผ 6์˜ ๊ณ ์˜จ๊ท ์—ด ํŒŒ๋ฉด๊ด€์ฐฐ ๊ฒฐ๊ณผ๋ฅผ ๋‚˜ํƒ€๋‚ธ๋‹ค. Varestraint ์‹œํ—˜ ์‹œ์˜ ์šฉ์œต์ง€ ๊ฒฝ๊ณ„์„  ๋‚ด๋ถ€์— ํ˜•์„ฑ๋œ ๊ท ์—ด์€ ์‘๊ณ ๊ท ์—ด๋กœ ํŒ๋ณ„๋˜์—ˆ๊ณ , ์—ด์˜ํ–ฅ๋ถ€์— ํ˜•์„ฑ๋œ ๊ท ์—ด์€ ์ž…๊ณ„ํŒŒ๊ดด(intergranular)์™€ ๋ฏธ์„ธ๋”คํ”Œ ํ˜•์ƒ์˜ ์ž…๋‚ดํŒŒ๊ดด(transgranular)๊ฐ€ ํ˜ผ์žฌ๋œ ์ „ํ˜•์ ์ธ ์•กํ™”๊ท ์—ด ํŒŒ๋ฉด์˜ ํŠน์ง•์„ ๋ณด์ด๊ณ  ์žˆ๋‹ค. ์ฆ‰, Varestraint ์‹œํ—˜์— ์˜ํ•ด ํ˜•์„ฑ๋œ ์—ด์˜ํ–ฅ๋ถ€ ๊ณ ์˜จ๊ท ์—ด(๊ทธ๋ฆผ 6)์€ ๋ชจ๋‘ ์•กํ™”๊ท ์—ด๋กœ ํŒ๋ณ„๋˜์—ˆ๋‹ค.

๊ทธ๋ฆผ 8์€ ๊ทธ๋ฆผ 7์˜ ์•กํ™”๊ท ์—ด ํŒŒ๋ฉด โ€œAโ€ ์˜์—ญ์— ๋Œ€ํ•œ EPMA ๋ถ„์„๊ฒฐ๊ณผ์ด๋‹ค. ์„ ํ–‰์—ฐ๊ตฌ ๊ฒฐ๊ณผ์— ์˜ํ•˜๋ฉด, CM247LC ํ•ฉ๊ธˆ(์ฃผ์กฐ์žฌ) ๋‹จ์ธต์šฉ์ ‘๋ถ€์˜ ์•กํ™”๊ท ์—ด ํ˜„์ƒ์€ ์šฉ์ ‘ ์Šน์˜จ๊ณผ์ •์—์„œ ๋ฐœ์ƒํ•˜๋Š” ฮณ/ฮณ' ๊ณต์ •์กฐ์ง์˜ ๋ถ€๋ถ„์  ์•ก์ƒํ™” ๋ฐ MC ํƒ„ํ™”๋ฌผ ์กฐ์„ฑ์ ์˜ ์•ก์ƒํ™”์— ๊ธฐ์ธํ•˜๋Š” ๊ฒƒ์œผ๋กœ ๋ณด๊ณ ๋˜๊ณ  ์žˆ๋‹ค[4,11,12]. Pre-weld Varestraint ์‹œํ—˜ ๊ฒฐ๊ณผ๋กœ๋ถ€ํ„ฐ ํ™•์ธ๋œ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด ๋˜ํ•œ, ๊ทธ๋ฆผ 4,5์— ๋‚˜ํƒ€๋‚ธ pre-welding ๋ฏธ์„ธ์กฐ์ง ํŠน์ง•์œผ๋กœ ์ธํ•ด ํŒŒ๋ฉด์ƒ์—๋Š” MCํ˜• ํƒ„ํ™”๋ฌผ ๋ฐ ฮณ/ฮณ' ๊ณต์ •์กฐ์ง์˜ ์•ก์ƒํ™” ํ”์ ์ด ๋ช…ํ™•ํžˆ ํ™•์ธ๋˜๋Š” ์œ ์‚ฌํ•œ ๊ฒฐ๊ณผ์ž„์„ ํ™•์ธํ•  ์ˆ˜ ์žˆ๋‹ค.

3.3 CM247LC ํ•ฉ๊ธˆ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด ๋ฐœ์ƒ์˜จ๋„๋ฒ”์œ„

Pre-weld Varestraint ์‹œํ—˜์„ ํ†ตํ•ด ํ˜•์„ฑ๋œ ์ตœ๋Œ€๊ท ์—ด๊ธธ์ด๋ฅผ ํ†ตํ•ด ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด ๋ฐœ์ƒ์˜จ๋„๋ฒ”์œ„(LCTR)๋ฅผ ๋„์ถœํ•˜์˜€๋‹ค. ๋ถ€๊ฐ€๋ณ€ํ˜•๋ฅ ์— ๋”ฐ๋ฅธ ์ตœ๋Œ€๊ท ์—ด๊ธธ์ด ํ‰๊ฐ€ ๋ฐ ์—ดํ™”์ƒ์นด๋ฉ”๋ผ ๊ด€์ฐฐ ์‹œ์˜ ๋ฐฉ์‚ฌ์œจ ์ตœ์ ํ™” ๊ณผ์ • ๋“ฑ์— ๋Œ€ํ•ด์„œ๋Š” CM247LC ํ•ฉ๊ธˆ ๋‹จ์ธต์šฉ์ ‘ ์‹œ์˜ LCTR์„ ํ‰๊ฐ€ํ•œ ์ €์ž์˜ ์„ ํ–‰์—ฐ๊ตฌ์™€ ๋™์ผํ•œ ๋ฐฉ๋ฒ•์„ ์ ์šฉํ•˜์˜€๋‹ค[4,12]. ๊ทธ๋ฆผ 9๋Š” ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR์„ ๋‚˜ํƒ€๋‚ด๊ณ  ์žˆ์œผ๋ฉฐ, ์„ ํ–‰ ์—ฐ๊ตฌ๋กœ๋ถ€ํ„ฐ ๋ณด๊ณ ๋œ CM247LC ํ•ฉ๊ธˆ ๋‹จ์ธต์šฉ์ ‘๋ถ€ LCTR์„ ํ•จ๊ป˜ ๋น„๊ตํ•˜๊ณ  ์žˆ๋‹ค[4,11]. CM247LC ํ•ฉ๊ธˆ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR 280 K์€์ฃผ์กฐ์žฌ ๋‹จ์ธต์šฉ์ ‘๋ถ€ LCTR(620 K) ๋ณด๋‹ค๋Š” ์•ฝ 55% ์ถ•์†Œ, ์‹œํšจ ์—ด์ฒ˜๋ฆฌ์žฌ์˜ ๋‹จ์ธต์šฉ์ ‘๋ถ€ LCTR (65 K) ๋Œ€๋น„ ์•ฝ 320% ํ™•๋Œ€๋œ ๊ฒฐ๊ณผ์ž„์„ ์•Œ ์ˆ˜ ์žˆ๋‹ค. ํ•ด๋‹น ์—ฐ๊ตฌ๋กœ๋ถ€ํ„ฐ CM247LC ํ•ฉ๊ธˆ ๋ธ”๋ ˆ์ด๋“œ ์ œ์กฐ ์šฉ์ ‘ ์‹œ, ์ฃผ์กฐ์žฌ์—์„œ ๋ฐœ์ƒ ํ•˜๋Š” ์ƒ๋‹น๋Ÿ‰์˜ ์•กํ™”๊ท ์—ด์€ ์‹œํšจ์—ด์ฒ˜๋ฆฌ์— ๋”ฐ๋ฅธ LCTR ์ตœ์†Œํ™”(์ฃผ์กฐ์žฌ: 620 K โ†’ ์‹œํšจ์—ด์ฒ˜๋ฆฌ์žฌ: 65 K)๋ฅผ ํ†ตํ•ด ์–ต์ œ๊ฐ€๋Šฅํ•œ ๊ฒƒ์œผ๋กœ ๋ณด๊ณ ํ•˜๊ณ  ์žˆ์œผ๋‚˜[4,11], ๋ณด์ˆ˜์šฉ์ ‘๋ถ€๋Š” ๋ชจ์žฌ ์žฌ์šฉ์œต์— ์˜ํ•œ LCTR ํ™•๋Œ€๋ผ๋Š” ์ƒˆ๋กœ์šด ์ •๋Ÿ‰ ๊ฒฐ๊ณผ๋ฅผ ์ œ์‹œํ•˜๊ณ  ์žˆ๋‹ค. ๋ณธ ๊ฒฐ๊ณผ๋Š” ๋ธ”๋ ˆ์ด๋“œ ์žฌ์ƒ ๊ณต์ •์—์„œ๋Š” ๊ฐ ์—ด์˜ํ–ฅ๋ถ€์˜ ์•กํ™”๊ท ์—ด ๋ฏผ๊ฐ๋„ ๋ณ€ํ™”๋ฅผ ๋ฉด๋ฐ€ํ•˜๊ฒŒ ๊ฒ€ํ† ํ•  ํ•„์š”๊ฐ€ ์žˆ์Œ์„ ์‹œ์‚ฌํ•œ๋‹ค.

๋ณด์ˆ˜์šฉ์ ‘๋ถ€์˜ ๊ณ ์˜จ๊ท ์—ด ๋ฏผ๊ฐ๋„๋ฅผ ํ‰๊ฐ€ํ•˜๊ธฐ ์œ„ํ•œ ๋‹ค์–‘ํ•œ ์„ ํ–‰์—ฐ๊ตฌ ๊ฒฐ๊ณผ๋“ค์ด ๋ณด๊ณ ๋์ง€๋งŒ, ๋Œ€๋ถ€๋ถ„์ด ์—ด๊ฐ„ ๋…ธ์ถœ์— ์˜ํ•œ ๋ณด์ˆ˜์šฉ์ ‘ ์ดˆ์ธต ์—ด์˜ํ–ฅ๋ถ€ ๊ณ ์˜จ๊ท ์—ด ๊ฑฐ๋™์— ๊ด€ํ•œ ๋‚ด์šฉ๋“ค์ด๋‹ค. ๋Œ€ํ‘œ์ ์œผ๋กœ Nishimoto et al.์€ Inconel 690 ํ•ฉ๊ธˆ ๋‹ค์ธต ์šฉ์ ‘๋ถ€๋ฅผ ์žฌํ˜„ํ•˜์—ฌ, ์šฉ์ ‘๋ถ€์˜ ๊ณ ์˜จ ์‹œํšจ์ •๋„๊ฐ€ ๋ณด์ˆ˜ ์šฉ์ ‘ ์‹œ์˜ ์—ฐ์„ฑ์ €ํ•˜๊ท ์—ด ๋ฏผ๊ฐ๋„์— ๋ฏธ์น˜๋Š” ์˜ํ–ฅ์„ ๊ฒ€ํ† ํ•˜์˜€๊ณ  [13], Chun et al. ๋˜ํ•œ 316FR ์Šคํ…Œ์ธ๋ฆฌ์Šค๊ฐ• ์šฉ์ ‘๋ถ€์˜ ์‹œ๊ทธ๋งˆ์ƒ ์ทจ์„ฑ๊ฑฐ๋™ ์ •๋„๊ฐ€ ๋ณด์ˆ˜์šฉ์ ‘ ์‹œ์˜ ๊ณ ์˜จ๊ท ์—ด ๊ฑฐ๋™์— ๋ฏธ์น˜๋Š” ์˜ํ–ฅ์„ ๊ฒ€ํ† ํ•˜์˜€๋‹ค[14]. ์ด๋Ÿฌํ•œ ๊ธฐ์กด์˜ ์—ฐ๊ตฌ๊ฒฐ๊ณผ์™€ ๋‹ฌ๋ฆฌ, pre-weld Varestraint ์‹œํ—˜ ๋ฐ ํ•ด๋‹น ํ‰๊ฐ€๊ฒฐ๊ณผ๋Š” ๋ณด์ˆ˜์šฉ์ ‘ ์ œ2์ธต ์—ด์˜ํ–ฅ๋ถ€์˜ ๊ณ ์˜จ๊ท ์—ด ๋ฏผ๊ฐ๋„๋ฅผ ์ฒด๊ณ„์ ์œผ๋กœ ์ œ์‹œํ•˜๊ณ  ์žˆ๋Š” ๋ฐ”, ๋ณธ ์—ฐ๊ตฌ ๊ฒฐ๊ณผ๋Š” ๊ธฐ์กด์˜ ํ‰๊ฐ€์ ˆ์ฐจ์™€ ํ•จ๊ป˜ CM247LC ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ ๋ธ”๋ ˆ์ด๋“œ์˜ ๋ฉด๋ฐ€ํ•œ ๋ณด์ˆ˜์šฉ์ ‘์„ฑ ๊ฒ€ํ† ์— ์ž˜ ํ™œ์šฉ๋  ์ˆ˜ ์žˆ์„ ๊ฒƒ์œผ๋กœ ์‚ฌ๋ฃŒ๋œ๋‹ค.

3.3.1 ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR ๋ณ€ํ™” ๊ธฐ๊ตฌ: MC ํƒ„ํ™”๋ฌผ ๋ถ„์œจ๊ณผ LCTR ์ƒ๊ด€๊ด€๊ณ„

CM247LC ํ•ฉ๊ธˆ ์šฉ์ ‘ ์Šน์˜จ ์‹œ ์—ด์˜ํ–ฅ๋ถ€์— ์กด์žฌํ•˜๋Š” 2์ฐจ์ƒ๋“ค ์ค‘, MCํ˜• ํƒ„ํ™”๋ฌผ์˜ ๊ตญ๋ถ€ ์•ก์ƒํ™” ์‹œ์ž‘์˜จ๋„๊ฐ€ ํƒ€ ์กฐ์ง ๋Œ€๋น„ ๊ฐ€์žฅ ๋‚ฎ์€ ๊ฒƒ์œผ๋กœ ๋ณด๊ณ ๋˜๊ณ  ์žˆ๋Š” ๋ฐ”[11], ๊ทธ๋ฆผ 9์— ๋‚˜ํƒ€๋‚ธ LCTR๊ณผ MC ํƒ„ํ™”๋ฌผ ๋ถ„์œจ์˜ ์ƒ๊ด€๊ด€๊ณ„๋ฅผ ํ†ตํ•ด ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR์„ ๊ณ ์ฐฐํ•˜์˜€๋‹ค. ๊ทธ๋ฆผ 10์€ EBSD๋กœ ๋ถ„์„ํ•œ MC ํƒ„ํ™”๋ฌผ ๋ถ„์œจ๊ณผ LCTR ์˜ ๊ด€๊ณ„๋ฅผ ๊ทธ๋ž˜ํ”„๋กœ ๋‚˜ํƒ€๋‚ด๊ณ  ์žˆ๋‹ค. ๊ทธ๋ฆผ 4์— ๋‚˜ํƒ€๋‚ด๋“ฏ์ด, pre-welding๋ถ€์˜ MC ํƒ„ํ™”๋ฌผ์€ 0.9%, CM247LC ํ•ฉ๊ธˆ ์ฃผ์กฐ์žฌ ๋ฐ ์‹œํšจ์—ด์ฒ˜๋ฆฌ์žฌ์˜ MC ํƒ„ํ™”๋ฌผ ๋ถ„์œจ์€ ์ €์ž์˜ ์„ ํ–‰์—ฐ๊ตฌ ๊ฒฐ๊ด๊ฐ’์„ ์‚ฌ์šฉํ•˜์˜€๋‹ค[4]. LCTR๊ณผ MC ํƒ„ํ™”๋ฌผ ๋ถ„์œจ ์‚ฌ์ด์—๋Š” ๋†’์€ ์ƒ๊ด€๊ด€๊ณ„๊ฐ€ ํ™•์ธ๋˜์—ˆ์œผ๋ฉฐ, ๋”ฐ๋ผ์„œ ๋ณธ ์—ฐ๊ตฌ์—์„œ ๋„์ถœ๋œ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR(280 K)๊ฐ€, ์ฃผ์กฐ์žฌ ๋ฐ ์‹œํšจ์—ด์ฒ˜๋ฆฌ์žฌ LCTR ๊ณผ ์ฐจ์ด๋ฅผ ๋ณด์ด๋Š” ๊ฒƒ์€, MC ํƒ„ํ™”๋ฌผ ๋ถ„์œจ์— ์˜์กดํ•˜๋Š” ๊ฒฐ๊ณผ๋กœ ํŒ๋‹จ๋œ๋‹ค.

3.3.2 ๋ณด์ˆ˜ ์šฉ์ ‘๋ถ€ LCTR ๋ณ€ํ™” ๊ธฐ๊ตฌ: ๋ฏธ๋Ÿ‰, ๋ถˆ์ˆœ๋ฌผ์›์†Œ ํŽธ์„๋†๋„์™€ LCTR ์ƒ๊ด€๊ด€๊ณ„

CM247LC ํ•ฉ๊ธˆ์„ ํฌํ•จํ•œ Ni๊ณ„ ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ์€, ๊ฒฐ์ •๋ฆฝ๊ณ„์— ์กด์žฌํ•˜๋Š” ๋ฏธ๋Ÿ‰(B) ๋ฐ ๋ถˆ์ˆœ๋ฌผ ์›์†Œ(S,P)๊ฐ€ ฮณ-ฮณโ€™ ๋ฐ ฮณMC ๋“ฑ์˜ ์ €์œต์  ์ƒ ์•ก์ƒํ™” ๋ฐ˜์‘ ์‹œ์ž‘์˜จ๋„๋ฅผ ์ €ํ•˜์‹œํ‚ค๊ณ , ์ด๋Š” ์šฉ์ ‘ ์‹œ ์•กํ™”๊ท ์—ด ๋ฏผ๊ฐ๋„๋ฅผ ๋ณด๋‹ค ์‹ฌํ™”์‹œํ‚ค๋Š” ๊ฒƒ (=LCTR ํ™•๋Œ€)์œผ๋กœ ์ž˜ ์•Œ๋ ค์ ธ ์žˆ๋‹ค[12,15]. ๊ทธ๋ฆผ 8์— ๋‚˜ํƒ€๋‚ธ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ ์•กํ™”๊ท ์—ด ํŒŒ๋ฉด์—์„œ๋„ ๋ฏธ๋Ÿ‰ ๋ฐ ๋ถˆ์ˆœ๋ฌผ ์›์†Œ(B,S)์˜ ์กด์žฌ๋Š” ๋ช…ํ™•ํžˆ ํ™•์ธ ๊ฐ€๋Šฅํ•˜๋‹ค. ํŠนํžˆ, pre-welding๋ถ€์— ์กด์žฌํ•˜๋Š” ์ƒ๊ธฐ ์›์†Œ์˜ ์–‘์€ ์‘๊ณ ๊ณผ์ • ์ƒ์˜ ๋ฏธ์„ธํŽธ์„ ๊ฑฐ๋™์— ์˜์กดํ•  ๊ฒƒ์œผ๋กœ ํŒ๋‹จ๋˜๋Š” ๋ฐ”, ์‘๊ณ ํŽธ์„ ๊ฑฐ๋™ ๊ฒ€ํ† ๋ฅผ ํ†ตํ•ด ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR์„ ์ถ”๊ฐ€์ ์œผ๋กœ ๊ณ ์ฐฐํ•˜์˜€๋‹ค. ์ด๋ฅผ ์œ„ํ•ด ์ฃผ์กฐ์žฌ์˜ ์‘๊ณ ํŽธ์„ ๊ฑฐ๋™๋„ ํ•จ๊ป˜ ๊ณ ๋ คํ•˜์˜€๋‹ค. Pre-welding ๋ฐ ์ฃผ์กฐ ์‘๊ณ ๊ณผ์ •(solidification path)์ƒ์˜ ๋ฏธ๋Ÿ‰, ๋ถˆ์ˆœ๋ฌผ ์›์†Œ ํŽธ์„๊ฑฐ๋™์€ ์ด๋ก ์ ์œผ๋กœ ๊ณ„์‚ฐํ•˜์˜€๋‹ค. Thermo-Calc(๋ฐ์ดํ„ฐ๋ฒ ์ด์Šค: TCNI9)์˜ Scheil ๋ชจ๋ธ์„ ํ† ๋Œ€๋กœ ๊ณ„์‚ฐํ•˜์˜€๊ณ , ์šฉ์ ‘ ๋ฐ ์ฃผ์กฐ ์‘๊ณ ํŠน์„ฑ ๋ฐ˜์˜์„ ์œ„ํ•ด ๋ƒ‰๊ฐ ์†๋„์™€ ํ™•์‚ฐ ์ œ์–ด๊ฐ€ ๊ฐ€๋Šฅํ•œ ์†๋„๋ก  ๋ฐ์ดํ„ฐ๋ฒ ์ด์Šค(kinetic database: MOBNI5)๋ฅผ ์ ์šฉํ•˜์˜€๋‹ค. ๊ณ„์‚ฐ ์‹œ์˜ ์ž…๋ ฅ ๋ณ€์ˆ˜๋Š” ํ‘œ 4์— ์š”์•ฝํ•˜์˜€๋‹ค. Pre-welding ์‹œ์˜ ๋ƒ‰๊ฐ์†๋„๋Š” ๋ณธ ์ €์ž์˜ ์„ ํ–‰์—ฐ๊ตฌ์—์„œ ์‚ฌ์šฉ๋œ CM247LC ์šฉ์ ‘์‘๊ณ  ๋ƒ‰๊ฐ์†๋„ ์ธก์ •๊ฐ’์„ ์‚ฌ์šฉํ•˜์˜€๊ณ [10], ์ฃผ์กฐ์žฌ ๋ƒ‰๊ฐ์†๋„๋Š” CM247LC ํ•ฉ๊ธˆ์„ ํฌํ•จํ•œ Ni๊ณ„ ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ ์ฃผ์กฐ ์‘๊ณ  ์‹œ์˜ ์ด์ฐจ์ˆ˜์ง€์ƒ ๊ฐ„๊ฒฉ (secondary dendrite arm spacing)๊ณผ ๋ƒ‰๊ฐ์†๋„์— ๋Œ€ํ•œ ์‹คํ—˜์‹์„ ๊ธฐ๋ฐ˜์œผ๋กœ ๋„์ถœํ•˜์˜€๋‹ค[3].

๊ทธ๋ฆผ 11์€ (a)B ๋ฐ (b)S ์›์†Œ์— ๋Œ€ํ•œ ์‘๊ณ ํŽธ์„ ๊ณ„์‚ฐ ๊ฒฐ๊ณผ๋ฅผ ๋‚˜ํƒ€๋‚ธ๋‹ค. ์‘๊ณ ๊ฐ€ ์ง„ํ–‰๋จ์— ๋”ฐ๋ผ ๊ธฐ์ง€์ƒ์ธ ฮณ ๋‚ด์˜ ๊ฐ ์›์†Œ๋†๋„๋Š” ์ฆ๊ฐ€ํ•˜๋Š” ์ถ”์ด๋ฅผ ๋ณด์ด๋ฉฐ, ์‘๊ณ  ์™„๋ฃŒ์‹œ์ (์‘๊ณ  ์ง„ํ–‰๋ฅ : 99.9%)์˜ ์ตœ์ข… ํŽธ์„๋†๋„๋Š” pre-welding (B: 0.0158 mass%, S: 1.94 ร— 10-6 mass%) ๋Œ€๋น„ ์ฃผ์กฐ์žฌ(B: 0.0170 mass%, S: 2.03 ร— 10-6 mass%)๊ฐ€ ๋†’์€ ๊ฒƒ์œผ๋กœ ํ™•์ธ๋˜์—ˆ๋‹ค. ๋”ฐ๋ผ์„œ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€์˜ LCTR์€ MC ํƒ„ํ™”๋ฌผ ๋ถ„์œจ ๋ณ€ํ™”๋ฟ๋งŒ ์•„๋‹ˆ๋ผ, pre-welding ์‹œ์˜ B, S ์›์†Œ ์‘๊ณ  ํŽธ์„๋Ÿ‰์— ํ•จ๊ป˜ ์˜์กดํ•˜๋Š” ๊ฒƒ์œผ๋กœ ํŒ๋‹จ๋œ๋‹ค.

์ฆ‰, 280 K ๋ผ๋Š” CM247LC ํ•ฉ๊ธˆ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR์€, ์ดˆ์ธต ์šฉ์œต์— ์˜ํ•œ MC ํƒ„ํ™”๋ฌผ ์ฆ๊ฐ€ ๋ฐ B, S ์›์†Œ์˜ ์‘๊ณ  ํŽธ์„ ๋ฐœ์ƒ์œผ๋กœ ์ธํ•ด ์‹œํšจ์ฒ˜๋ฆฌ์žฌ ๋‹จ์ธต์šฉ์ ‘๋ถ€ LCTR ๋Œ€๋น„ 245 K ์ฆ๊ฐ€ํ•˜์ง€๋งŒ, ์ฃผ์กฐ์žฌ ๋‹จ์ธต์šฉ์ ‘๋ถ€ LCTR ๋Œ€๋น„ MC ํƒ„ํ™”๋ฌผ ๋ฐ B, S ์›์†Œ์˜ ์‘๊ณ ํŽธ์„๋Ÿ‰ ๊ฐ์†Œ๋กœ 380 K ์ถ•์†Œ๋œ ๊ฐ’์„ ๊ฐ€์ง€๋Š” ๊ฒƒ์œผ๋กœ ํŒ๋‹จ๋œ๋‹ค.

4. ๊ฒฐ ๋ก 

๋ณธ ์—ฐ๊ตฌ์—์„œ๋Š” ์ƒˆ๋กญ๊ฒŒ ๊ณ ์•ˆํ•œ pre-weld Varestraint ์‹œํ—˜์„ ์ด์šฉํ•ด CM247LC ์ดˆ๋‚ด์—ดํ•ฉ๊ธˆ ๊ฐ€์Šคํ„ฐ๋นˆ ๋ธ”๋ ˆ์ด๋“œ ๋ณด์ˆ˜ ์šฉ์ ‘ ์‹œ์˜ ์ œ2์ธต ์—ด์˜ํ–ฅ๋ถ€ ์•กํ™”๊ท ์—ด ๋ฏผ๊ฐ๋„๋ฅผ ์ •๋Ÿ‰ ํ‰๊ฐ€ํ•˜์˜€๋‹ค. ํ‰๊ฐ€ ๊ฒฐ๊ณผ๋Š” pre-welding ์‹œ์˜ ์šฉ์ ‘๊ธˆ์† ๋ฏธ์„ธ์กฐ์ง๊ณผ ์—ด์—ญํ•™์  ์šฉ์ ‘์‘๊ณ  ๊ณ„์‚ฐ์„ ์—ฐ๊ณ„ํ•˜์—ฌ ๋ชจ์žฌ์˜ ๋‹จ์ธต์šฉ์ ‘ ์•กํ™”๊ท ์—ด ๊ฑฐ๋™์— ๋Œ€ํ•œ ์„ ํ–‰์—ฐ๊ตฌ ๊ฒฐ๊ณผ์™€ ๋น„๊ต ๊ณ ์ฐฐํ•˜์˜€๋‹ค. ์•„๋ž˜์™€ ๊ฐ™์ด ๋ณธ ์—ฐ๊ตฌ์˜ ๊ฒฐ๋ก ์„ ์š”์•ฝํ•œ๋‹ค.

A. CM247LC ํ•ฉ๊ธˆ pre-welding๋ถ€์— ๋Œ€ํ•œ Varestraint ์‹œํ—˜์„ ํ†ตํ•ด ๋ณด์ˆ˜์šฉ์ ‘ ์ œ2์ธต ์—ด์˜ํ–ฅ๋ถ€๋ฅผ ๋ชจ์‚ฌํ•˜์˜€๊ณ , Varestraint ์‹œํ—˜ ๊ท ์—ด ํ˜•์„ฑ ์‹œ์ ์˜ ์˜จ๋„๊ฐ€์‹œํ™”๋ฅผ ํ†ตํ•ด ์•กํ™” ๊ท ์—ด ๋ฏผ๊ฐ๋„, ์ฆ‰ LCTR์„ ํ‰๊ฐ€ํ•  ์ˆ˜ ์žˆ์—ˆ๋‹ค. ๊ทธ ๊ฒฐ๊ณผ CM247LC ํ•ฉ๊ธˆ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR์€ 280 K๋กœ ํ‰๊ฐ€๋˜์—ˆ๋‹ค. ํ•ด๋‹น ๊ฒฐ๊ณผ๋Š” CM247LC ํ•ฉ๊ธˆ ๋ธ”๋ ˆ์ด๋“œ ๋‹จ์ธต ์ œ์กฐ์šฉ์ ‘ ์‹œ์˜ LCTR (์ฃผ์กฐ์žฌ 620 K, ์‹œํšจ ์—ด์ฒ˜๋ฆฌ์žฌ 65 K)๊ณผ ํฐ ์ฐจ์ด๋ฅผ ๋ณด์ด๋ฉฐ, ์ด๋Š” ๋ชจ์žฌ์˜ ๊ท ์—ด ๋ฏผ๊ฐ๋„์™€๋Š” ๋ณ„๋„๋กœ ๋ณด์ˆ˜์šฉ์ ‘ ์‹œ์—๋Š” ์—ด์˜ํ–ฅ๋ถ€ ์œ„์น˜๋ณ„ ์•กํ™”๊ท ์—ด ๊ฑฐ๋™์„ ๋ฉด๋ฐ€ํ•˜๊ฒŒ ๊ฒ€ํ† ํ•  ํ•„์š”๊ฐ€ ์žˆ์Œ์„ ์‹œ์‚ฌํ•œ๋‹ค.

B. ๋ฏธ์„ธ์กฐ์ง ๋ถ„์„ ๋ฐ Scheil์‹ ์‘๊ณ ๊ณ„์‚ฐ ๊ฒฐ๊ณผ, CM247LC ํ•ฉ๊ธˆ ๋ณด์ˆ˜์šฉ์ ‘๋ถ€ LCTR์€ pre-welding ๊ณผ์ •์˜ MC ํƒ„ํ™”๋ฌผ ๋ถ„์œจ๊ณผ B,S ๋ฏธ๋Ÿ‰ ๋ถˆ์ˆœ๋ฌผ ์›์†Œ ์‘๊ณ ํŽธ์„๋Ÿ‰์— ์˜์กดํ•˜๋Š” ๊ฒƒ์œผ๋กœ ํŒ๋ช…๋˜์—ˆ์œผ๋ฉฐ, ์ฆ‰ ์‹ค์ œ ๋ณด์ˆ˜์šฉ์ ‘ ์‹œ์—๋Š” MC ํƒ„ํ™”๋ฌผ๊ณผ ํ•ด๋‹น ์›์†Œ์˜ ์‘๊ณ ํŽธ์„์ด ์ €๊ฐ ๊ฐ€๋Šฅํ•œ ๊ณต์ • ์„ค๊ณ„๊ฐ€ ํ•„์š”ํ•  ๊ฒƒ์œผ๋กœ ์‚ฌ๋ฃŒ๋œ๋‹ค.

C. ์ƒ๊ธฐ ๊ฒฐ๊ณผ๋ฅผ ํ†ตํ•ด ๋ณธ ์—ฐ๊ตฌ์—์„œ ๊ณ ์•ˆํ•œ pre-weld Varestraint ์‹œํ—˜ ํ‰๊ฐ€ ์ ˆ์ฐจ ๋ฐ ํ•ด๋‹น ๊ฒฐ๊ณผ์˜ ์‹ ๋ขฐ์„ฑ์„ ํ™•์ธํ•  ์ˆ˜ ์žˆ์—ˆ์œผ๋ฉฐ, ์ด๋Š” ํ–ฅํ›„ CM247LC ํ•ฉ๊ธˆ์˜ ๊ฐ€์Šคํ„ฐ๋นˆ ๋ธ”๋ ˆ์ด๋“œ ๋ณด์ˆ˜์šฉ์ ‘ ๋ฐ ๊ณ ๊ฑด์ „์„ฑ ์šฉ์ ‘๋ถ€ ์ œ์กฐ์— ์žˆ์–ด ์œ ํšจํ•œ ์•กํ™” ๊ท ์—ด ๋ฏผ๊ฐ๋„ ํ‰๊ฐ€ ๋ฐฉ๋ฒ•์œผ๋กœ ํ™œ์šฉ๋  ๊ฒƒ์œผ๋กœ ํŒ๋‹จ๋œ๋‹ค.

Acknowledgements

๋ณธ ์—ฐ๊ตฌ๋Š” ์‚ฐ์—…ํ†ต์ƒ์ž์›๋ถ€์˜ ์žฌ์›์œผ๋กœ ํ•œ๊ตญ์‚ฐ์—…๊ธฐ์ˆ ํ‰๊ฐ€๊ด€๋ฆฌ์›(์ „๋žตํ•ต์‹ฌ์†Œ์žฌ์ž๋ฆฝํ™”๊ธฐ์ˆ ๊ฐœ๋ฐœ์‚ฌ์—…(No.20011103),๊ธฐ๊ณ„์‚ฐ์—…ํ•ต์‹ฌ๊ธฐ์ˆ ๊ฐœ๋ฐœ์‚ฌ์—…(No.20015063)) ๋ฐ ํ•œ๊ตญ์—๋„ˆ์ง€๊ธฐ์ˆ ํ‰๊ฐ€์›(์—๋„ˆ์ง€์ธ๋ ฅ์–‘์„ฑ์‚ฌ์—…(No.20214000000480))์˜ ์ง€์›์„ ๋ฐ›์•„ ์ˆ˜ํ–‰๋˜์—ˆ์Œ. ๊ณผํ•™๊ธฐ์ˆ ์ •๋ณดํ†ต์‹ ๋ถ€์˜ ์žฌ์›์œผ๋กœ ํ•œ๊ตญ์—ฐ๊ตฌ์žฌ๋‹จ(๊ฐœ์ธ์—ฐ๊ตฌ์ง€์›์‚ฌ์—…(No. 2019R1G1A1099607))์˜ ์ง€์›์„ ๋ฐ›์•„ ์ˆ˜ํ–‰๋˜์—ˆ์Œ.

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Figures and Tables

Fig. 1.

Schematic description for repair welding of CM247LC alloy turbine blade and objective of this study (HAZ: heat-affected zone).

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f1.jpg
Fig. 2.

(a) appearance and (b) schematic illustration of the Varestraint test with GTAW

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f2.jpg
Fig. 3.

Procedures of pre-weld Varestraint test; (a) side and (b) cross-sectional view.

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f3.jpg
Fig. 4.

Cross-sectional microstructure characterized via EBSD for CM247LC welds (IQ: image quality, IPF: inverse pole figure).

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f4.jpg
Fig. 5.

Back-scattered electron (BSE) image and elemental distributions analyzed by EPMA at the fusion zone (region โ€œAโ€ denoted in Fig. 4) of CM247LC welds.

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f5.jpg
Fig. 6.

Appearance and liquation cracking behavior after the pre-weld Varestraint test.

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f6.jpg
Fig. 7.

Characterization of a liquation cracking surface after the pre-weld Varestraint test.

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f7.jpg
Fig. 8.

Back-scattered electron (BSE) image and elemental distribution behavior at fracture surface of a liquation crack after pre-weld Varestraint test.

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f8.jpg
Fig. 9.

Relationship between condition of testing materials and liquation cracking temperature range (*: adopted from Ref. 4,11).

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f9.jpg
Fig. 10.

Relationship between fraction of MC-type carbide and liquation cracking temperature range (*: adopted from Ref. 4).

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f10.jpg
Fig. 11.

Calculated solidification segregation behavior of (a) B and (b) S for the conditions of pre-welding and casting of CM247LC alloy.

../../Resources/kim/KJMM.2022.60/kjmm-2022-60-4-272f11.jpg
Table 1.

Chemical composition of material used (mass%).

Material Ni C Cr Co Mo W Ta Ti Al B Zr Hf P S
CM247LC Bal. 0.07 8.1 9.2 0.5 9.5 3.2 0.7 5.6 0.015 0.015 1.4 <0.0006 <0.0002
Table 2.

Conditions of the pre-weld Varestraint test.

Parameters Conditions
Pre-welding Welding Autogenous GTAW
Arc voltage 18 V
Arc current 100 A
Arc length 1 mm
Welding speed 1 mm/s
Shield gas Argon (99.99% purity)
Varestraint test Welding Spot GTAW
Arc voltage 18 V
Arc current 60 A
Arc length 2 mm
Welding time 10 s
Shield gas Argon (99.99% purity)
Bending strain 0.5โ€“3.0%
Bending rate 400 mm/s
Table 3.

Specifications of the infrared-thermovision camera used.

Parameter Conditions
Resolution 640 ร— 480 pixels at 50 Hz
640 ร— 240 pixels at 100 Hz
640 ร— 120 pixels at 200 Hz
Detector Uncooled microbolometer
Minimum focus distance 0.25 m
Spectral range 7.5โ€“14 (Long-wave infrared)
Temperature acquisition range 298โ€“2273 K
Response time < 8 ms
Temperature accuracy ยฑ2 K
Emissivity 0.6
Table 4.

Conditions of Scheil calculation by Thermo-calc (*: adopted from Ref. 10).

Input parameters Values
CM247LC (Pre-welding) Cooling rate 146.3 K/s (*)
Solidification completion rate 99.9%
CM247LC (As-cast) Cooling rate 2.8 K/s
Secondary dendrite arm spacing 24.3 ยตm (measured)
Solidification completion rate 99.9%